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Karbothermische und metallothermische Reduktion von hochschmelzenden Metallen im Vakuum (Forschungsberichte des Landes Nordrhein-Westfalen, 2376) (German Edition) by Helmut Winterhager
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Die Elemente der IV. bis VI. Nebengruppe des periodischen Systems sind aIle im Vergleich zu Eisen ausgepriigte Karbidbildner. Das wird deutlich. wenn man die Freien Bildungsenthalpien der entsprechenden Metallkarbide neben der des Eisenkarbids betrachtet (Tabelle 1) Tabelle 1: F reie Bildungsenthalpien der Karbide der Elemente aus der IV. bis VI. Nebengruppe im Vergleich mit Eisenkarbid 0 0 bei 298 K und 1500 K Verbindung Freie Bildungsenthalpie aus den Elementen is G /f cal/mol] A G /[ call mol] 298 1500 TiC - 43 030 - 40 130 ZrC - 43 440 - 40 800 V C - 34 900 - 33 700 2 - 21 750 - 19 950 VC 75 O . VC - 23 650 - 21 850 Nb C - 45 700 - 44 500 2 NbC - 33 120 - 31 200 Ta C - 46 850 - 46 250 2 - 28 600 - 30 520 TaCO 7 .
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